DSE Chemistry

DSE Chemistry: Materials Chemistry (Elective) — Practice Questions & Answers

How structure determines properties, the chemistry of polymers and plastics, the special behaviour of nanomaterials, and the design and selection of materials.

336 practice questions available for this topic — here are 10 with full answers and explanations.

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Practice questions with answers

1 Multiple choice · Easy

Kevlar and nylon-6,6 are both examples of

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WhyBoth are polyamides, joined by amide (peptide) linkages.
2 Multiple choice · Medium

The type of reaction that forms Kevlar from its two monomers is

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WhyPolyamides form by condensation polymerisation, releasing small molecules such as water.
3 Multiple choice · Hard

Kevlar is made from a diamine and a benzene-1,4-dicarboxylic acid (or its dichloride). The two functional groups that react to form the amide link are

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WhyAn amine (-NH2) and a carboxylic acid (-COOH) react to form the -CONH- amide link.
4 Fill in the blank · Easy

The linkage joining the monomer units in nylon-6,6 and Kevlar is the linkage.

Answer: amide / peptide

WhyAmide linkage.
5 Fill in the blank · Medium

In a condensation polymerisation forming a polyamide, the small molecule eliminated is usually .

Answer: water / H2O / hydrogen chloride / HCl

WhyWater (or HCl if an acid chloride is used).
6 Fill in the blank · Hard

Nylon-6,6 is made from a and a dicarboxylic acid, each having two reactive groups.

Answer: diamine / diamine monomer

WhyDiamine.
7 Multiple choice · Medium

How many atoms are there in one body-centred cubic (bcc) unit cell?

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Why8 corner atoms x 1/8 + 1 body-centre atom = 2 atoms per bcc unit cell.
8 Multiple choice · Medium

In a body-centred cubic unit cell, each corner atom is shared between how many neighbouring unit cells?

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WhyEach corner atom is shared among 8 unit cells, contributing 1/8 to each.
9 Multiple choice · Hard

For a bcc unit cell, the contribution of the atom at the body centre to that cell is

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WhyThe body-centre atom lies wholly inside one cell, contributing 1.
10 Fill in the blank · Medium

A body-centred cubic unit cell contains atoms in total.

Answer: 2 / two

Why2 atoms.

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Key terms in Materials Chemistry (Elective)

Material: A substance chosen for a particular use based on its physical and chemical properties.
Plastic: A synthetic polymer that can be moulded into shape, made from many repeating monomer units.
Polymer: A large molecule built from many repeating monomer units joined by covalent bonds.
Monomer: A small molecule that joins with many others to form a polymer.
Addition polymerisation: The joining of unsaturated monomers to form a polymer with no loss of atoms.
Condensation polymerisation: The joining of monomers to form a polymer with the loss of a small molecule.
Thermoplastic: A polymer that softens on heating and can be remoulded repeatedly.
Thermosetting plastic: A cross-linked polymer that sets hard on heating and cannot be remoulded.

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