DSE Chemistry

DSE Chemistry: Chemical Equilibrium — Practice Questions & Answers

Reversible reactions and dynamic equilibrium, the effects of concentration, pressure and temperature predicted by Le Chatelier's principle, and industrial conditions.

294 practice questions available for this topic — here are 10 with full answers and explanations.

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Practice questions with answers

1 Multiple choice · Medium

Which statement about a chemical system at dynamic equilibrium is correct?

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WhyAt dynamic equilibrium the forward and backward reactions occur at equal rates, keeping concentrations constant.
2 Multiple choice · Medium

Increasing the reaction temperature does NOT increase the yield of every reversible reaction because

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WhyRaising temperature shifts an exothermic forward reaction towards the reactants, lowering its yield even though equilibrium is reached faster.
3 Multiple choice · Hard

For the equilibrium Fe3+(aq) + SCN-(aq) reversible Fe(SCN)2+(aq), adding Na3PO4(s) removes Fe3+ as insoluble FePO4. The equilibrium position will

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WhyRemoving Fe3+ shifts the equilibrium to the left to replace it, so Fe(SCN)2+ decomposes.
4 Fill in the blank · Medium

When writing an equilibrium constant Kc expression, pure solids and pure liquids are .

Answer: omitted / left out / excluded

WhyOnly species whose concentrations can vary are included.
5 Fill in the blank · Easy

The value of the equilibrium constant Kc changes only when the is changed.

Answer: temperature

WhyConcentration and pressure changes do not alter Kc.
6 Fill in the blank · Medium

Removing a product from an equilibrium mixture shifts the position of equilibrium to the to replace it.

Answer: right / products / product side

WhyThis follows Le Chatelier's principle.
7 Multiple choice · Medium

For X2(g) + 3Y2(g) reversible 2XY3(g), which combination shows the effect of a catalyst on the rate of forward reaction, rate of backward reaction and the yield of XY3?

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WhyA catalyst increases both rates equally and leaves the yield unchanged.
8 Multiple choice · Easy

A catalyst added to a reversible reaction at equilibrium

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WhyIt only shortens the time to reach equilibrium.
9 Multiple choice · Hard

Why does a catalyst leave the equilibrium yield unchanged?

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WhyIt speeds the forward and backward reactions to the same extent.
10 Fill in the blank · Easy

A catalyst allows a reaction to reach equilibrium more .

Answer: quickly / rapidly / fast

WhyIt speeds attainment of equilibrium.

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Key terms in Chemical Equilibrium

Reversible reaction: A reaction that can proceed in both the forward and backward directions.
Dynamic equilibrium: The state where forward and reverse reactions occur at equal rates and concentrations stay constant.
Forward reaction: The reaction proceeding from reactants to products as written.
Backward reaction: The reaction proceeding from products back to reactants.
Closed system: A system that can exchange energy but not matter with its surroundings, required for equilibrium.
Equilibrium constant (Kc): A value giving the ratio of product to reactant concentrations at equilibrium for a given temperature.
Equilibrium expression: The formula relating Kc to the concentrations of products and reactants raised to their coefficients.
Position of equilibrium: The relative amounts of reactants and products present at equilibrium.

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